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IIT-G develops cost-effective, efficient solar cells

The emerging perovskite-based semiconducting devices are considered the most promising due to their low-cost, ease of manufacturing as roll-to-roll devices, high material availability and easy recyclability

Indian Institute of Technology, Guwahati
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Indian Institute of Technology, Guwahati

New Delhi/Guwahati: Indian Institute of Technology, Guwahati researchers have developed hybrid perovskite-based solar or photovoltaic devices, which are highly efficient, cost effective, easy to manufacture and easily recyclable when it comes to producing electricity from the sunlight.

The emerging perovskite-based semiconducting devices are considered the most promising due to their low-cost, ease of manufacturing as roll-to-roll devices, high material availability and easy recyclability.

These devices were developed achieving power conversion efficiencies beyond 21 per cent by utilizing economical solution-based photovoltaic device processing techniques at mild room temperature and realizing high ambient, thermal and optical stability.

Among all the renewable energy sources, the energy from sun (solar energy) is considered to be the most sustainable due to its ample availability on the surface of the earth. Currently, inorganic solar cell (Silicon-based) is a major player in the market. However, this technology requires high-temperature processing, which results in the high price of solar panels. Further, the recycling of solar panels is hazardous and complicated. "The perovskite solar cells (PSCs) research has experienced tremendous attention due to their exponential growth in terms of efficiencies achieved within a decade. However, the perovskite materials are extremely unstable towards ambient (humidity and oxygen) conditions that restrict their commercialization," said a release from IIT-Guwahati.

The research team at IIT-Guwahati comprising research scholars Rabindranath Garai (Department of Chemistry), Ritesh Kant Gupta (Centre for Nanotechnology), Arvin Sain Tanwar (Department of Chemistry) and Maimur Hossain (Department of Chemistry), all working under the supervision of Professor Parameswar K. Iyer, Department of Chemistry and Centre for Nanotechnology and School for Health Science and Technology, IIT Guwahati, have achieved the results in terms of efficiency and stability of the PSCs.

In this recent study of IIT-Guwahati, published in the American Chemical Society journal 'Chemistry of Materials' mentioned how charged conjugated polymers have been incorporated in photovoltaic devices as a passivation molecule to achieve defect-free high-quality perovskite solar cell devices.

The passivated defect-free device reveals a high efficiency of 20.17 per cent with excellent reproducibility. Such polymer based passivation method effectively improved the long-term device stability by improving the hydrophobicity of the perovskite layer.

In another recent investigation by the team, published in The Royal Society of Chemistry journal 'Journal of Materials Chemistry A', the researchers demonstrated the development of solution-processed multi-dimensional (2D-3D) graded perovskites and the precise role of surface re-crystallisation to achieve very high efficiencies, stability, economical device scalability by mitigating the perovskite defects.

Speaking about these research output, Prof Iyer said that organic-inorganic hybrid PSCs have experienced rapid growth in terms of efficiency and stability due to the development of highly efficient functional materials combined with careful device engineering.

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